Antireflection coating for ultraviolet light at large angles of incidence

ABSTRACT

Antireflection multilayer coatings with only three or four layers are proposed for the production of laser resistant optical components with minimal residual reflection and high transparency for UV light in a wavelength range approx. 150 nm to approx. 250 nm at large angles of incidence in the range of approx. 70° to approx. 80°, particularly in the range between approx. 72° and approx. 76°. For incident p-polarized UV light three-layer systems can be used, in which a layer of low refractive material, in particular magnesium fluoride is arranged between two layers of high refractive material and, in the case of the specified wavelength, of minimally absorbent material, in particular of hafnium oxide or aluminum oxide. For example, this allows a residual reflection of perceptibly less than 1% to be achieved in the case of a wavelength of 248 nm at angles of incidence in the range between approx. 72° and approx. 76°.

The following disclosure is based on German Patent Application No. 10064 143.1, filed on Dec. 15, 2000, which is incorporated into thisapplication by reference.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The invention relates generally to an optical component with a lowreflectance for ultraviolet light in a wavelength range between approx.150 nm and approx. 250 nm at large angles of incidence, in particularbetween approx. 70° and approx. 80°.

2. Description of the Related Art

In many areas the need is increasing for powerful optical componentswith a low reflectance and high transparency or transmission forultraviolet light in a wavelength range between approx. 150 nm andapprox. 250 nm. Light from this wavelength range is used for example inmicrolithographic exposure systems for the production of highlyintegrated semiconductor components with the aid of wafer steppers orwafer scanners. In the process via an illumination system a light sourceilluminates a mask (reticle), the image of which is reproduced with theaid of a projection system onto a photoresist coated semiconductorwafer. As it is a known fact that the miniaturization achievable withthis process increases the shorter the wavelength λ of the light used,in the most modern devices wavelengths from the deep ultraviolet range(Deep Ultraviolet, DUV) are used. Light sources for this are KrF excimerlasers with a working wavelength of λ=248 nm and ArF excimer lasers witha working wavelength of approx. λ=193 nm. These lasers generate linearpolarized light, which, in the case of a diagonal incidence on a surfaceof an optical component, occurs either as s-polarized or p-polarizedlight, according to the individual surface orientation.

As is known the surfaces of transparent optical components are coatedwith so-called antireflection layers or antireflection layers (ARlayers) to increase their transparency for light. Usually, in theprocess, multilayer systems consisting of several stacked layers ofdielectric materials with various refractive indexes are used, in whichlayers of a high refractive material and layers of a relatively lowrefractive material are usually stacked alternately on top of eachother.

Whereas for an effective reduction of reflection in the case of avertical incidence of light a few layers can suffice if suitable layermaterials are selected, experience shows that the number of layersrequired increases the bigger the angle of incidence Θ, i.e. the anglebetween the direction of the incidence of light and the surface normal.This effect is shown for example in EP 0 855 604, in which theantireflection layers for UV light in the wavelength range between 150nm and 250 nm at large angles of incidence between 70° and 80° arerevealed. The multilayer systems proposed there are characterized inthat the optical thickness of the layers of high refractive material isalways the same and the optical thickness of the intermediate layers oflow refractive materials is always the same, so that a periodic layersequence results. Examples are shown for p-polarized light with awavelength of λ=193 nm, according to which in order to minimize theresidual reflection to values of below approx. 0.5% at an angle ofincidence of Θ=72° seven layers are required, at an angle of incidenceof Θ=74° nine layers are required and at an angle of incidence of 76°even eleven layers are required. In the case of p-polarized light with awavelength of λ=248 nm two additional layers each are required for thecorresponding angles of incidence.

The practical use of optical components with antireflection multilayersis frequently influenced by the fact that these types of multilayersystems only show limited resistance when subjected to intensivehigh-energy UV radiation. As a result, the problem of the lacking laserresistance is pushed all the more to the fore the greater the energydensity of the incident light. High energy densities of laser lightoccur for example in the field of devices for narrowing the bandwidth ofexcimer lasers. In U.S. Pat. No. 5,978,409 such a device is exemplarilyshown, in which an arrangement of three or four prisms is provided towiden a laser beam before incidence on an echelle grate, on thehypotenuse surfaces of which the laser light always is incident with alarge angle of incidence. In the case of an optimal configuration withregard to the achievable beam widening three prisms are provided, on thehypotenuse surfaces of which the UV light always impacts with angles ofincidence of approx. Θ=74°. As for this configuration in the case of awavelength of 193 nm, no sufficient laser resistant antireflection layeris available, uncoated prisms would have to be used, which would howeverlead to overall losses of more than 40% due to reflection in the case ofthe available substrate materials (CaF₂ or synthetic quartz) and adouble passage through the prisms. Therefore, as an alternative, anembodiment with four prisms is proposed, on the hypotenuse surfaces ofwhich the laser light is incident with smaller angles of incidencebetween approx. 67° and approx. 71°. To reduce the reflection a singlelayer of Al₂O₃ is always applied to the surfaces, which has sufficientlaser resistance and is also intended to lead to a sufficient reductionin reflection. However, the residual reflection can not be reduced belowapprox. 3% via such a single layer for angles of incidence of approx.74°.

It is an object of the invention to provide an antireflection coatingfor optical components, which allows an effective antireflection coatingfor ultraviolet light in a wavelength range between approx. 150 nm andapprox. 250 nm at large angles of incidence in the range of approx. 70°to approx. 80° and is characterized by high laser resistance.

SUMMARY OF THE INVENTION

As a solution to this object the invention proposes an optical componenthaving low reflectance for ultraviolet light of a wavelength in a rangebetween approx. 150 nm and approx. 250 nm at large angles of incidence,the optical component comprising: a substrate comprising at least onesurface; a multilayer system consisting of several stacked layers andapplied to the at least one surface of the substrate; a layer of themultilayer system consisting of one of a high refractive dielectricmaterial and a low refractive dielectric material; the multilayer systemcomprising less than five layers.

Embodiments are specified in the dependent claims. The verbatim of allclaims is incorporated by reference into the subject matter of thedescription.

In accordance with one aspect of the invention an optical component witha low reflectance for UV light is created from the specified wavelengthrange at large angles of incidence by applying a multilayer system, i.e.a multilayer coating with several stacked layers, which always consistsof dielectric material transparent for the UV light, to at least onesurface of an optical substrate for the reduction of reflection. Thelayer materials are high refractive or low refractive, wherein a highrefractive material has a higher refractive index in comparison with therefractive index of the other layer material and a low refractivematerial has a lower refractive index in comparison with the other layermaterial. Frequently, the refractive index of the substrate materiallies between those of the layer materials. The multilayer system hasless than five layers. Preferably only three or four layers areprovided.

Due to the low number of layers in comparison with known multilayersystems the laser resistance of the coating can be improved only by thefact that the probability of errors leading to layer degradation in themultilayer system is usually lower, the lower the number of layersapplied. The type of errors, which decrease the laser resistance, can inparticular be impurities, defects or inclusions, which increase thelocal absorption and can thus lead to an uneven radiation load on thelayer. A reduction in the number of layers leads to a processsimplification, which can reduce the costs for the provision of thecoated optical components according to invention.

The layer adjacent to the substrate, which is also described in thefollowing as the first layer, preferably consists of a high refractivematerial so that in the case of three-layer systems with alternatinghigh refractive and low refractive layers, the outer, third layer alsoconsists of high refractive material, whereas in the case of four-layersystems with alternating high and low refractive material an outer layerof low refractive material is adjacent to the medium surrounding theoptical component.

It is a known fact that there are only a few materials which have asufficiently high refractive index in the considered wavelength rangebetween approx. 150 nm and 250 nm, to allow a sufficiently largerefraction coefficient ratio for an effective multilayer coating incomparison with the available low refractive layer materials. Therefractive index or the refraction coefficient n of the high refractivematerials for the provided wavelength is preferably at values of n≧1.7,in particular at values of n≧2.0. As a preference metal oxides are usedas high refractive materials, which due to strong compounds have arelatively high specific laser resistance.

A particular aspect of the invention is that in the case of preferredembodiments of the antireflection coatings that serve to increasetransmission, one or more layers, in particular the high refractionlayers can consist of materials, which absorb the incident light to asmall extent. Such materials are expediently described with a complexrefractive index n=n−ik, wherein n is the real refractive index and k isthe absorption index or the extinction coefficient at considered workingwavelength. This is usually below 10⁻⁶ in the case of the so-callednon-absorbent materials. It has been shown that in order to avoidnegative effects of absorption it usually suffices to select thosematerials in which the absorption coefficient k is greater than 10⁻⁶ or10⁻⁵, but less than 0.01, in particular less than 0.005, wherein thosematerials are preferred, in which k is not significantly greater than0.001.

The knowledge that slightly absorbent materials can also be used toadvantage in the case of transmission increasing antireflection coatingshas opened new dimensions in layer design, as the range of availablematerials, in particular those with a high refractive index isexpanding. These advantages can also be used in multilayer systems withmore than three or four layers and/or at other angles of incidence thanthose cited. With regard to the aspired increase in the laserdestruction threshold, it should also be taken into consideration thatthis is indeed influenced by the absorption coefficients of thematerials, but that the coating structure influencing the interferenceeffects and the production process also influence the absorptioncoefficient of the coating.

In preferred embodiments of the coatings for a wavelength of 248 nmaccording to the invention, hafnium oxide (HfO₂) is used as highrefractive material. Hafnium oxide has a real refractive index n ofapprox. 2.1 in this wavelength range, however it also has absorption inthis wavelength range and, for this reason among others, was previouslynot used for antireflection coatings. The absorption coefficient k isapprox. 0.001. In the embodiments it is shown that when using hafniumoxide as a high refractive layer material for diagonal incident UV lightwith a wavelength of 248 nm a reduction of reflection of far below 0.5%residual reflection is possible, wherein the residual reflectionpractically disappears at an angle of incidence of Θ=74°. The absorptioncan be in the order of magnitude of approx. 0.2%, so that such coatedtransparent components can have a transmission coefficient greater than99% or greater than 99.5%.

For example, zirconium oxide (ZrO₂), which has an absorption coefficientin the order of magnitude of k=0.01 in the case of a real refractioncoefficient n of approx. 2.2, can be used as an alternative.

In the case of multilayer systems for a wavelength of 193 nm aluminumoxide (Al₂O₃) is used preferably as high refractive layer material,which at this wavelength has a real refractive index in the order ofmagnitude of approx. n=1.7 and an absorption coefficient of approx.k=0.001. Other materials with similar optical properties can also besuitable.

The influence of absorption, in particular on the transmission and thelayer heating can be kept to a minimum by keeping the overall thicknessof the layers of high refractive and, if necessary, absorbent materialto a minimum, for example, with overall layer thicknesses of the highrefractive layers of less than 100 nm. The overall thickness can, forexample, be less than 50 nm when using hafnium oxide or less than 70 nmwhen using aluminum oxide.

It is possible to use layer thicknesses, the optical thickness of whichdeviates from a quarter wavelength layer thickness (“quarterwave” layerthickness). If necessary, all layers of the multilayer system can havedifferent physical thicknesses. However, multilayer systems are alsopossible in which the layers of the same material also have the sameoptical thickness.

Fluorides are used preferably as low refractive materials, in particularmagnesium fluoride (MgF₂). Possible alternatives such as calciumfluoride, sodium fluoride, lithium fluoride or aluminum fluoride areconceivable, insofar as the refractive index of the appropriate materialis lower than that of the high refractive material and, if necessary, ofthe substrate material. Suitable substrate materials for transparentoptical components are above all silicon oxide as glass (syntheticquartz) or single crystalline materials such as calcium fluoride ormagnesium fluoride and also, if necessary, barium fluoride.

These and other features result from the description and the drawings aswell as from the claims, wherein each of the individual features canalways be realized individually or together in the form ofsub-combinations in an embodiment of the invention and in other fieldsand can represent advantageous, as well as protectable embodiments.

Embodiments of the invention are portrayed in the drawings and aredescribed in more detail in the following. Shown are:

FIG. 1 a schematic section through a antireflection layer with threelayers applied to a transparent substrate for the reduction ofreflection a wavelength of 248 nm and large angles of incidence in therange of approx. 74°,

FIG. 2 a diagram, which shows measured values for the reflectance of thelayer portrayed in FIG. 1 as a function of the angle of incidence Θ,

FIG. 3 a diagram, which shows the measured values for the reflectance asa function of the angle of incidence Θ for a wavelength of λ=193 nm fora three-layer system with aluminum oxide as high refractive material,

FIG. 4 a schematic section through a antireflection layer with fourlayers on a transparent substrate,

FIG. 5 a diagram, which shows a comparison of calculated values for thereflectance of multiple layers as a function of the angle of incidenceat λ=248 nm, wherein a triple layer is used for p-polarized light and aquadruple layer is used for s-polarized light; and

FIG. 6 a diagram which shows a comparison of calculated values for thereflectance of multiple layers as a function of the angle of incidenceat λ=193 nm, wherein a triple layer is used for p-polarized light and aquadruple layer is used for s-polarized light.

FIG. 1 contains a schematic section through the surface area of anoptical component 1, which has a substrate 2 made of a materialtransparent for ultraviolet light with a wavelength of 248 nm. On theshown flat surface 3 of the substrate, which can for example be thehypotenuse surface of a prism, a multilayer antireflection coating 4with three stacked layers 5, 6, 7 is applied.

The substrate consists of a single crystalline calcium fluoride (CaF₂)with a refractive index of n=1.47, i.e. a refractive index similar tothat of alternatively usable materials such as e.g. synthetic quartzglass (SiO₂) with n=1.5. The first layer 5 applied directly to thesurface 3 of the substrate consists essentially of hafnium oxide (HfO₂)which has a relatively high refractive index of n=2.1 at a wavelength ofλ=248 nm. The high refractive layer 5 adjacent to the substrate is witha physical layer thickness of approx. 10 nm very thin in comparison withthe “quarterwave layer thicknesses” usually used for antireflectioncoatings and is only approx. ⅓ of this “quarterwave layer thickness”.The second layer 6 above consists essentially of magnesium fluoride(MgF₂) which, in comparison with substrate 2, has a low refractive indexof approx. n=1.41. The layer thickness of layer 6 consisting of lowrefractive material is at 94.4 nm almost ten times that of the thinfirst layer 5, wherein this layer thickness is equivalent to more thandouble the corresponding “quarterwave layer thickness” (43.7 nm MgF₂).The outer third layer 7, which is usually adjacent to air, anothergaseous medium or vacuum, with a refractive index of approx. n=1 againconsists of hafnium oxide, but in comparison with layer 5 adjacent tothe substrate, has approx. the triple layer thickness (28.8 nm), whichis equivalent to the “quarterwave layer thickness” for hafnium oxide at248 nm.

The layers of the examples shown and all those following are applied tothe substrate 2 via the usual method of physical vapor deposition (PVD)in vacuum. To apply the coating any other suitable technique can also beused.

The three-layer system exemplarily shown here is characterized incomparison with conventional known systems for antireflection coatingpurposes among other things in that with hafnium oxide a coatingmaterial is used, which, in the provided wavelength range (λ=248 nm),shows a minimal but measurable absorption. Whereas in the case ofconventional non-absorbent materials the absorption coefficient k hastypical values of below 10⁻⁶, the absorption coefficient of hafniumoxide is approx. k=10⁻³ at λ=248 nm. It has been shown that thisdisadvantage has practically no effect whatsoever and is perceptiblyoutweighed by the advantage of the high refractive index of thematerial. In addition, the overall absorption can be kept to a minimumif the overall thickness of the layers consisting of absorbent materialis kept to a minimum. In the example this overall layer thickness oflayers 5 and 7 is less than 40 nm, which means that typicaldisadvantages expected for absorbent materials such as intensifiedheating of the layers and the associated layer degradation practicallydo not occur. Endurance tests to achieve laser resistance in whichlayers with similar layer structure are subjected to laser pulses withenergy densities of approx. 30 mJ/cm², show no layer degradation, tears,or other degradations, even after several billion pulses, which verifiesthe laser resistance of these layers.

Significant optical properties of the three-layer antireflection coatingshown are explained with the aid of the measuring diagram in FIG. 2.There the reflectance R is shown (as a percentage) of the layer systemshown in FIG. 1 dependent on the angle of incidence Θ, in whichp-polarized UV light is incident with a wavelength of λ=248 nm. Inaccordance with the convention the angle of incidence Θ describes theangle between the surface normal 8 and the direction of incidence 9,both designate the plane of incidence, in which the vector of theelectrical field of the incident UV light oscillates. It can bediscerned that the reflectance of the surface coated with thethree-layer antireflection coating 4 in the angle of incidence rangebetween approx. 70.5° and approx. 75.5° is below 1% and in the rangebetween approx. 72° and approx. 74.5° is perceptibly below 0.5%. In theangle range between approx. 72.5° and approx. 74° an almost completeantireflection coating is achieved, in which the residual reflection isbelow approx. 0.3%. The influence of the absorption is very low atapprox. 0.2%, so that in the angle range between approx. 72.5° and 74°transmission coefficients of 99.5% or better can be achieved.

The layer design exemplarily explained with the aid of FIG. 1 isrelatively tolerant as regards small variations of the layer thicknessessuch as can those which can occur due to process fluctuations during thecoating. Thus, for example, thickness changes of approx ±5% onlyinsignificantly alter the reflectance by approx. 0.3%. Essentially,identical layer thicknesses of the high refractive material are alsopossible. A triple layer with 21.5 nm HfO₂ as first layer, 99.7 nm MgF₂as second layer and 21.5 nm HfO₂ as third layer has similar opticalproperties. As an alternative to hafnium oxide other dielectricsubstances or material combinations with similar optical properties canbe used, for example zirconium oxide. If necessary, instead of themagnesium fluoride layer, a layer of another low refractive material incomparison with the substrate can be used. Advantageous is thealternating sequence of high refractive and low refractive material,wherein the layer adjacent to the substrate should have a higherrefractive index than the substrate material.

At a wavelength of 193 nm the absorption of hafnium oxide or similarmaterials is such as high that these materials cannot be used or canonly be used in exceptional cases for antireflection coatings. At thesewavelengths another three-layer system (not illustrated) has proveditself, in which aluminum oxide was used as a high refractive substance.

This layer system also consists only of three layers, wherein a highrefractive aluminum oxide layer is directly adjacent to the CaF₂substrate and a thicker layer of magnesium oxide is arranged betweenthis and the outer aluminum oxide layer. In the case of an embodimentthe optical properties of which are explained with the aid of themeasuring diagram of FIG. 3, a layer of magnesium fluoride with athickness of 45 nm is arranged between two layers of aluminum oxide ofthe same thickness with layer thicknesses of 31.5 nm each. It can bediscerned from FIG. 3 that in the case of this layer system and incidentp-polarized light with a wavelength of λ=193 nm the minimum residualreflection is at an angle of incidence of approx. 69° to 70°, at whichthe residual reflection is less than 0.1%. Also, in the case ofdeviations of ±2° from this optimal angle of incidence residualreflections of less than 0.5% are still achieved, wherein for examplethe residual reflection is still less than 1% at an angle of incidenceof Θ=72°.

It can be discerned that in the case of the triple layer systemsaccording to the invention the minimum residual reflection moves itselfto smaller angles of incidence the shorter the wavelength of theincident light. However, even at a wavelength of 193 nm and angles ofincidence of 74° a substantial antireflection coating can still beachieved in comparison with an uncoated substrate, as in the case of thetriple layer coating shown in FIG. 3 the residual reflection is approx.1.8%, whereas in the case of an uncoated CaF₂ substrate it is approx.R=8%.

With the aid of FIGS. 4 to 6 it is now exemplarily explained that on thebasis of the exemplarily explained triple layers effectiveantireflection coatings for the specified wavelength and angle ofincident ranges can also be generated for s-polarized light by theapplication of a single additional layer of low refractive material.Moreover, FIG. 4 shows a schematic section through the surface area ofan optical component 10, which essentially differs from the opticalcomponent 1 in FIG. 1 in that an antireflection coating 11 with fourstacked layers 5, 6, 7, 12 is applied to surface 3 of the substrate 2.The three layers 5, 6, 7 adjacent to the substrate are identical to thelayers 5, 6, 7 from FIG. 1 with regard to the layer material and onlydiffer from them due to minimal differences in thickness. The layerthickness of the hafnium oxide layer 5 adjacent to the substrate isapprox. 14 nm, that of the magnesium fluoride layer 6 above approx. 109nm and that of the hafnium oxide layer 7 above approx. 30 nm. On top ofthis a magnesium fluoride layer 12 of approx. 53 nm layer thickness isapplied as an outer layer.

The optical properties of the four-layer antireflection coating 11 areexplained with the aid of FIG. 5, which shows the reflectance R as afunction of the angle of incidence Θ for incident UV light with awavelength of 248 nm. The continuous line of the curve in FIG. 2 showsappropriately calculated values for the reflectance of the triple layerin FIG. 1 for p-polarized light, whereas the broken line in FIG. 4 showsappropriate values of the quadruple layer shown in FIG. 4 fors-polarized light. It can be discerned that the quadruple coating 11reduces the residual reflection to values of below 1% for angles ofincidence between approx. 71° and approx. 78°, wherein the residualreflection in the range between approx. 73.5° and approx. 76° is below0.3% and has a minimum of 0.1% at approx. 75°.

FIG. 6 shows an appropriate diagram for UV light with λ=193 nm, whereinthe continuous line corresponds to the measuring curve from FIG. 3 andalso represents a triple layer, in which a layer of magnesium fluoridewith a thickness of approx. 45 nm is always arranged between a layeradjacent to the substrate and an outer layer of aluminum oxide of 31.5nm each. On this layer system an additional layer of magnesium fluoridewith a layer thickness of approx. 45 nm is applied to improve thereflectance reduction in the case of s-polarized light. This periodiclayer structure, in which the layer thicknesses of the high refractiveminimally absorbent material (aluminum oxide) and the low refractivematerial (magnesium oxide) are the same, reduces the residual reflectionto values of below 1% in the case of s-polarized light in the anglerange between approx. 71° and approx. 75°, wherein between approx. 72°and approx. 76° the residual reflection is less than 0.5% andessentially disappears at approx. 74°.

Reflex reducing multilayer coatings with only three or four layers areproposed for the production of laser resistant optical components withminimal residual reflection for UV light in a wavelength range approx.150 nm to approx. 250 nm at large angles of incidence in the range ofapprox. 70° to approx. 80°, particularly from the range between approx.72° and 76°. For incident p-polarized UV light three-layer systems canbe used to advantage, in which a layer of low refractive material, inparticular magnesium fluoride, is arranged between two layers of highrefractive material, in particular of hafnium oxide or aluminum oxide.An optimization of the reflectance reduction for s-polarized light canbe achieved via the application of an additional layer of low refractivematerial.

A particular aspect of the invention is based upon the knowledge that inthe case of multilayer antireflection coatings not only so-callednon-absorbent materials (with typical absorption coefficients k of below10⁻⁶) can be used, but also those materials which show a low absorption,as long as the absorption coefficient k does not significantly exceedvalues of 0.01, in particular 0.001. In particular, materials such ashafnium oxide or, if necessary, zirconium oxide can be used forwavelengths of approx. λ=248 nm, wherein it is expedient to only aspireto minimal overall layer thicknesses of perceptibly less than 100 nm, inorder to avoid negative effects of absorption. These conditions could beadhered to, particularly in the case of multilayer systems with onlyfew, for example three of four, layers in any case.

Tests have shown that an antireflection multilayer coating with an outersituated layer of aluminum oxide is also advantageous with regard to theavoidance or reduction of contamination effects. It is a known fact thatunder the influence of short wave ultraviolet radiation on conventionalcoating materials such as magnesium fluoride a surface deposit formsafter a certain period of time, which reduces the life of the opticalelements used and can lead to an increased amount of diffused light. Forexample, a deposit formation of ammonium salts and other impurities isknown from U.S. Pat. No. 5,685,895. In radiation tests in whichantireflection multilayer coatings with an outer aluminum oxide layerwere compared with appropriate multilayer coatings and an outer layer ofanother material it emerged that an outer deposit protection layer ofaluminum oxide led to a perceptibly measurable delay in contamination.This enabled the proof to be furnished that a top layer of aluminumoxide (Al₂O₃) can significantly reduce the rate of salification onoptical surfaces under UV radiation. Thus, the invention alsoencompasses a process to protect coated optical components against theformation of deposit, which is characterized in that an outer layer ofaluminum oxide is applied to a multilayer coating. In addition, the useof aluminum oxide as an outer protective layer against the formation ofdeposits on multilayer coatings is proposed. This surprising andadvantageous effect against the formation of deposits is independent ofthe number of layers of the optical multilayer system and can inparticular also be used to advantage in antireflection multilayersystems with five or more layers.

The above description of the preferred embodiments has been given by wayof example. From the disclosure given, those skilled in the art will notonly understand the present invention and its attendant advantages, butwill also find apparent various changes and modifications to thestructures and methods disclosed. It is sought, therefore, to cover allsuch changes and modifications as fall within the spirit and scope ofthe invention, as defined by the appended claims, and equivalentsthereof.

What is claimed is:
 1. Optical component having low reflectance forultraviolet light of a wavelength in a range between approx. 150 nm andapprox. 250 nm at large angles of incidence, the optical componentcomprising: a substrate comprising at least one surface; a multilayersystem comprising several stacked layers and applied to the at least onesurface of the substrate; a layer of the multilayer system consisting ofeither a high refractive dielectric material or a low refractivedielectric material; the multilayer system comprising at least one layermade of a slightly absorbent material having an absorption coefficient kof more than 10⁻⁶ at the wavelength of the incident ultraviolet light.2. Optical component according to claim 1, wherein the absorptioncoefficient k is less than 0.01.
 3. Optical component according to claim1, wherein the absorption coefficient k is not significantly greaterthan 0.001.
 4. Optical component according to claim 1, wherein theslightly absorbent material is a metal oxide.
 5. Optical componentaccording to claim 1, wherein the slightly absorbent material isselected from the group consisting of hafnium oxide and aluminum oxide.6. Method for manufacturing an optical component with a low reflectancefor ultraviolet light in a wavelength range between approx. 150 nm andapprox. 250 nm, the method comprising: providing a substrate having atleast one surface; depositing on the at least one surface of thesubstrate an anti-reflective multilayer system by depositing severallayers comprising dielectric material, wherein a layer consists ofeither a high refractive dielectric material or a low refractivematerial; wherein said depositing step comprises depositing at least onelayer consisting of a slightly absorbent material having an absorptioncoefficient k of more than 10⁻⁶ for the incident ultraviolet light.